Question Bank No: 1

1. Which of the following substance is insoluble in water but gives crystalline precipitate with hydrochloric acid?

 a)Methyl amine
 b)Acetamide
 c)Aniline
 d)Dimethyl amine

2. Which of the following amine will not react with benzoyl chloride?

 a)Isopropyl amine
 b)p-toludine
 c)N,N-Diethyl aniline
 d)N-methyl aniline

3. Which of the following amine is stronger base as compared to ammonia?

 a)Cyclohexylamine
 b)Benzenamine
 c)Diphenyl amine
 d)Triphenyl

4. The hybrid state of nitrogen in diethyl amine is

 a)Sp3
 b)Sp2
 c)sp
 d)sp3d

5. Which of the following reagent reacts only with primary amines?

 a)NaNO2/HCl
 b)CH3COCl
 c)CH3Mgl
 d)CH3CHO

6. Which is least reactive to nitration?

 a)Benzene
 b)Nitrobenzene
 c)Chlorobenzene
 d)Aniline

7. Which of the following reagent can distinguish between 10amine and 20amine?

 a)Br2/NaOH
 b)NaNO2/HCl
 c)NH3
 d)HClO4

8. The total number of σelectrons , πelectrons and lone pairs in one molecule of acrylonitrile are respectively

 a)12σ,6π,1LP
 b)6σ,3π,1LP
 c)8σ,6π,1LP
 d)6σ,6π,2LP

9. Which of the following amine will not react with diethyl oxalate?

 a)(CH3)2CHNH2
 b)C2H5NH2
 c)(C2H5)3N
 d)(C2H5)3CNH2

10. Which of the following reagent can be used to convert benzene diazonium chloride to benzene?

 a)Phosphorous acid
 b)Phosphoric acid
 c)Hypophosphoric acid
 d)Metaphosphoric acid

11. The most reactive compound out of the following towards electrophilic substitution of the ring is

 a)C6H5NO2
 b)C6H5NH2
 c)C6H5NH3Cl
 d)C6H5NHCOCH3

12. The main product of the reaction of ethyl bromide and alcoholic solution of silver nitrite is

 a)Ethyl cyanide
 b)nitroethane
 c)ethane
 d)ethyl nitrite

13. Which of the following treatment will yield azoxybenzene from nitrobenzene?

 a)Electrolysis in acidic conditions
 b)NaOH/Zn, CH3OH
 c)Sn/HCl
 d)Na3AsO3/NaOH

14. Which of the following has lowest value of pkb?

 a)CH3CH2NH2
 b)CH3CH2OH
 c)CH3CH2CONH2
 d)NH3

15. The main product of reduction of nitrobenzene with lithium aluminium hydride is

 a)Azoxybenzene
 b)Aniline
 c)Azobenzene
 d)Diazonium salt

16. Which of teh following on reaction with chloroform produces carbylamine?

 a)P-amine
 b)sec-amine
 c)tert-amine
 d)All of the above

17. A substance forms zwitter ion. It can have functional groups

 a)NH2,COOH
 b)NH2,SO3H
 c)both
 d)none of these

18. Baryer's Reagent is

 a)alkaline KMnO4solution
 b)Acidified KMnO4 solutions
 c)neutral KMnO4solutions
 d)aqueous bromine solutions

19. Carbylamine test is used in the detention of

 a)Aliphatic 20amine
 b)Armoatic 10amine
 c)Aliphatic 10amine
 d)Both Aliphatic and Armoatic 10amines

20. Which amine among the following will NOT undergo Carbylamine reaction?

 a)Ethylamine
 b)Methylamine
 c)Dimethylamine
 d)Phenylamine